(η5-Cyclopentadienyl)(η6-1,2-dipyrrolidin-1-ylbenzene)iron(II) hexafluoridophosphate
نویسندگان
چکیده
Both complexed rings in the iron(II) complex cation of the title salt, [Fe(C(5)H(5))(C(14)H(20)N(2))]PF(6), are almost parallel [dihedral angle between planes = 5.34 (13)°]. Among the C atoms of the complexed arene ring, the quaternary C atoms are located at the longest, albeit unequal, distances from the Fe atom [2.252 (2) and 2.168 (2) Å].
منابع مشابه
(η5-Cyclopentadienyl)[(1,2,3,4,4a,12a-η)-naphtho[2,3-b][1,4]benzodioxine]iron(II) hexafluoridophosphate
At 296 (2) K, both complexed rings in the iron(II) complex cation of the title salt, [Fe(C(5)H(5))(C(16)H(10)O(2))]PF(6), are almost parallel [dihedral angle between planes = 2.4 (3)°]. The quaternary C atoms of the complexed arene ring are located at the longest distance from the Fe atom, with Fe-C distances of 2.112 (4) and 2.105 (3) Å, which are slightly longer than the average Fe-C distance...
متن کامل(η5-Cyclopentadienyl)[η6-diethyl ethyl(phenyl)malonate]iron(II) hexafluoridophosphate
At 223 (2) K, the complexed rings in the iron(II) complex cation of the title salt, [Fe(C(5)H(5))(C(15)H(20)O(4))]PF(6), are almost parallel [dihedral angle between planes = 4.10 (14)°]. Among the C atoms of the complexed arene ring, the quaternary C atom is located at the longest distance from the Fe atom. The F atoms of the PF(6) (-) anion were found to be equally disordered over two sites.
متن کامل[1,2-Bis(dimethylphosphino)ethane]carbonyl(η5-cyclopentadienyl)iron(II) diphenylphosphinoylborate
In the title compound, [Fe(C(5)H(5))(C(6)H(16)P(2))(CO)](C(12)H(13)BOP), the Fe(II) ion adopts a three-legged piano-stool geometry, with Fe⋯Cg = 1.721 (5)Å (Cg = the centroid defined by the C atoms of the cyclo-penta-dienyl ring). The 1,2-bis-(dimethyl-phosphino)ethane (dmpe) ligand chelates to form a five-membered C(2)P(2)Fe ring which is in a pseudo-half-chair conformation. In the crystal str...
متن کامل(μ-Ethane-1,2-diamine-κ2 N:N′)bis[dicarbonyl(η5-cyclopentadienyl)iron(II)] bis(tetrafluoridoborate)
The asymmetric unit of the title compound, [Fe(2)(C(5)H(5))(2)(C(2)H(8)N(2))(CO)(4)](BF(4))(2), contains two half-cations, each located on a center of symmetry, and two tetra-fluorido-borate anions. The iron atoms adopt a three-legged piano-stool geometry. All amine H atoms are involved in N-H⋯F hydrogen bonds, which consolidate the crystal packing along with weak C-H⋯O and C-H⋯F inter-actions.
متن کامل(η5-Cyclopentadienyl)(η6-mesitylamine)ruthenium(II) hexafluoridophosphate
The title compound, [Ru(η(5)-C(5)H(5)){η(6)-C(6)H(2)(CH(3))(3)NH(2)}]PF(6), contains a sandwich complex with a mesitylamine unit which is significantly non-planar at the ipso-carbon of the amino group due to repulsive electronic effects with Ru. The ipso-carbon deviates by 0.107 (3) Å from the least-squares plane of the remaining five benzene ring atoms, which show an r.m.s. deviation of 0.005 ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009